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4-Carboxyphenylboronic acid

4-Carboxyphenylboronic acid structure

CAS No.: 14047-29-1

Chemical Name:: 4-Carboxyphenylboronic acid

Synonyms: 4-BORONOBENZOIC ACID;4-borono-benzoicaci;4-Carboxyphenylboronic;4-Carboxyphenylboronic acid, 97% 5GR;NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;4-CarboxyphenyL;ZERENEX ZX001647

CBNumber:: CB1312607

Molecular Formula:: C7H7BO4

Molecular Weight:: 165.94

MDL Number:: MFCD00151801

MOL File:: 14047-29-1.mol

MSDS File:: SDS

Last updated:2023-06-13 12:09:43

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4-Carboxyphenylboronic acid Properties

Melting point	220 °C (dec.) (lit.)
Boiling point	406.4±47.0 °C(Predicted)
Density	1.40±0.1 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka	4.08±0.10(Predicted)
form	Powder
color	Off-white to light beige
BRN	3031088
InChI	InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChIKey	SIAVMDKGVRXFAX-UHFFFAOYSA-N
SMILES	C(O)(=O)C1=CC=C(B(O)O)C=C1
CAS DataBase Reference	14047-29-1(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	XQQ1T11DYK

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H303-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Hazard Codes

Xi,Xn

Risk Statements

36/37/38-20/21/22

Safety Statements

37/39-26-36

WGK Germany

RTECS

CY8925000

TSCA

HazardClass

IRRITANT

HS Code

29319090

NFPA 704

	0
2		0

4-Carboxyphenylboronic acid price More Price(48)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	456772	4-Carboxyphenylboronic acid	14047-29-1	1g	$40.5	2023-06-20	Buy
Sigma-Aldrich	456772	4-Carboxyphenylboronic acid	14047-29-1	10g	$349	2023-06-20	Buy
TCI Chemical	C1353	4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)	14047-29-1	1g	$33	2023-06-20	Buy
TCI Chemical	C1353	4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)	14047-29-1	5g	$109	2023-06-20	Buy
Alfa Aesar	B20954	4-Carboxybenzeneboronic acid, 97%	14047-29-1	1g	$37.2	2023-06-20	Buy

Product number	Packaging	Price	Buy
456772	1g	$40.5	Buy
456772	10g	$349	Buy
C1353	1g	$33	Buy
C1353	5g	$109	Buy
B20954	1g	$37.2	Buy

4-Carboxyphenylboronic acid Chemical Properties,Uses,Production

Description

4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

Reference

Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

Chemical Properties

Off-white to light beige powder

Uses

suzuki reaction

Uses

4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.

Uses

Intermediates of Liquid Crystals

4-Carboxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID 4-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID 4-Carbamoylphenylboronic acid 4-AZIDOBENZOIC ACID 4-(1H-PYRAZOL-4-YL)BENZOIC ACID

4-Carboxylphenylboronic acid pinacol ester 4'-METHYLSULFANYL-BIPHENYL-4-CARBOXYLIC ACID 2'-ACETYL[1,1'-BIPHENYL]-4-CARBOXYLIC ACID 4-(8-Bromo-[1,7]naphthyridin-6-yl)-benzoic acid 2',3',5',6'-tetramethylterphenyl-4,4"-dicarboxylic acid

4-(1-Methyl-1H-pyrazol-3-yl)benzoic acid 4-(6-METHOXYPYRIDAZIN-3-YL)BENZOIC ACID

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4-Carboxyphenylboronic acid Suppliers

Global( 532)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Maison Chemical Co.,Ltd.	+8615511852758	sales@maisonchem.com.cn	China	451	58
Frapp's ChemicalNFTZ Co., Ltd.	+86 (576) 8169-6106	sales@frappschem.com	China	885	50
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29811	60
Henan DaKen Chemical CO.,LTD.	+86-371-66670886	info@dakenchem.com	China	18729	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21975	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
China Synchem Technology Co.,Ltd.	0552-4929304 18055277008	sales@cnsynchem.com	China	41	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	31969	60
Zjartschem	+86-571-8723 8903 jocelynpan@zjarts.com	jocelynpan@zjarts.com	CHINA	993	58

Supplier	Advantage
Hebei Maison Chemical Co.,Ltd.	58
Frapp's ChemicalNFTZ Co., Ltd.	50
Capot Chemical Co.,Ltd.	60
Henan DaKen Chemical CO.,LTD.	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
China Synchem Technology Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Zjartschem	58

View Lastest Price from 4-Carboxyphenylboronic acid manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-06-14	4-Carboxyphenylboronic acid 14047-29-1	US $9.00 / KG	1KG	99.9	1 ton	Hebei Crovell Biotech Co Ltd
2023-05-12	4-Carboxyphenylboronic acid 14047-29-1	US $0.00 / kg	1kg	99%	according to customer's requirements	Changzhou waston chemical technology Co.,Ltd
2023-05-04	4-Carboxyphenylboronic acid 14047-29-1	US $48.00-40.00 / KG	1KG	99%	200tons	Guangzhou Sunton Biotechnology Co., Ltd.

4-Carboxyphenylboronic acid
14047-29-1
US $9.00 / KG
99.9
Hebei Crovell Biotech Co Ltd

4-Carboxyphenylboronic acid
14047-29-1
US $0.00 / kg
99%
Changzhou waston chemical technology Co.,Ltd

4-Carboxyphenylboronic acid
14047-29-1
US $48.00-40.00 / KG
99%
Guangzhou Sunton Biotechnology Co., Ltd.

4-Carboxyphenylboronic acid Spectrum

4-Carboxyphenylboronic acid(14047-29-1)¹HNMR 4-Carboxyphenylboronic acid(14047-29-1)FT-IR

14047-29-1(4-Carboxyphenylboronic acid)Related Search:

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4-Ethoxycarbonyl-2-nitrophenylboronic acid 4-Carboxynaphthalene-1-boronic acid 4-ISOPROPOXYCARBONYLPHENYLBORONIC ACID 4-METHOXYCARBONYL-2,6-DIFLUOROPHENYLBORONIC ACID Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

4-Carboxylphenylboronic acid pinacol ester (2-AMINO-4-CARBOXYPHENYL)BORONIC ACID ETHYL 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE 4-(TERT-BUTOXYCARBONYL)PHENYLBORONIC ACID 4-Carboxyphenylboronic acid

2-Carboxybenzaldehyde Carboxy styrene-butadiene latex Phenylboronic acid

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4-borono-benzoicaci AKOS BRN-0008 RARECHEM AH PB 0147 TIMTEC-BB SBB003899 OTAVA-BB BB7110951390 P-CARBOXYPHENYLBORONIC ACID ZERENEX ZX001647 4-(Dihydroxyboronyl)benzoic acid, 4-Boronobenzoic acid 4-Carboxyphenylboron 4-(dihydroxyboryl)benzoic acid(SALTDATA: FREE) 4-Carboxyphenylboronic acid, 97% 5GR 4-(Dihydroxyboryl)benzoic acid, 4-Boronobenzoic acid 4-Carboxyborophenylic acid p-Carboxyborophenylic acid 4-Carboxyphenylboronic acid ,98% 4-Carboxyphenylboronic acid, min. 97% 4-Carboxyphenylboranic acid 4-boronobenzoic acid，4-Carboxyphenylboronic acid 4-Carboxyphenylboronic acid,97% 4 - carboxyl benzene boric acid hericium erinaceus p.e. 4-Carboxyphenylboronic acid 4-(Dihydroxyboryl)benzoic acid 4-Carboxylphenylboronic acid 44-Carboxyphenylboronic acid Benzeneboronic acid, p-carboxy- Benzoic acid, p-borono- WLN: VHOR DBQQ 4-Hydroxycarbonylphenyl boronic acid NSC 221170 Benzoic acid, 4-borono- AURORA 14935 IFLAB-BB F1371-0202 4-(DIHYDROXYBORYL)BENZOIC ACID 4-(DIHYDROXYBORANE)BENZOIC ACID 4-BORONOBENZOIC ACID 4-CARBOXYBENZENEBORONIC ACID 4-CARBOXYPHENYLBORONIC ACID 4-Carboxyphenylboronic acid D4 4-Carboxyphenylboronic acid≥ 99.5% (HPLC) p-borono-benzoicaci p-boronobenzoicacid p-carboxy-benzeneboronicaci p-carboxybenzeneboronicacid 4-(Dihydroxyboronyl)benzoic acid 4-Carboxypenylboronic Acid 4-darboxybenzeneboronic acid 4-Carboxyphenylboron dihydroxide 4-Carboxyphenylboronic 4-Carboxyphenylboronicacid,min.97% 4-CARBOXYBENZENEBORONIC ACID 98% 4-DIHYDROXYBORANYL-BENZOIC ACID 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Carboxyphenylboronic acid, 98%, for synthesis 4-CarboxyphenyL 4-Carboxyphenylboronicaci 4-Carboxyphenylboronic Acid extrapure, 97% 14047-29-1 Boronic Acids and Derivatives