|
|
| | (S)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol Basic information |
| Product Name: | (S)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol | | Synonyms: | (S)-(-)-ɑ,ɑ-Diphenylprolinol, 98%;(S)-2-(Hydroxydiphenylmethyl)pyrrolidine;alpha,alpha-diphenyl-L-proline;(S)-α,α-Diphenyl-2-pyrrolidinemethanol, (S)-2-(Diphenylhydroxymethyl)pyrrolidine;(S)-(-)-2-(Diphenylhydroxymethyl)pyrrolidine, α,α-Diphenyl-L-prolinol;(S)-(-)-Alpha,alpha-diphenyl-2-pyrrolidin emethanol, 99+%;(2S)-α,α-Diphenyl-2-pyrrolidinemethanol;(2S)-α,α-Diphenyl-2α-pyrrolidinemethanol | | CAS: | 112068-01-6 | | MF: | C17H19NO | | MW: | 253.34 | | EINECS: | 601-153-1 | | Product Categories: | Peptide;Asymmetric Synthesis;Chiral Building Blocks;Simple Alcohols (Chiral);Synthetic Organic Chemistry;CHIRAL CHEMICALS;chiral;Chiral Reagent;Chiral Reagents;Benzenes;Chiral chemicals;Pharmaceutical intermediate;Chiral Nitrogen | | Mol File: | 112068-01-6.mol |  |
| | (S)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol Chemical Properties |
| Melting point | 77-80 °C(lit.) | | alpha | -59 º (c=3, methanol 25 ºC) | | Boiling point | 396.54°C (rough estimate) | | density | 1.0078 (rough estimate) | | refractive index | -66.5 ° (C=3, CHCl3) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Soluble in chloroform. | | form | powder | | pka | 13.15±0.29(Predicted) | | color | white to off white ., crystal | | optical activity | [α]20/D 67°, c = 3 in chloroform | | Merck | 14,155 | | BRN | 17103 | | InChIKey | OGCGXUGBDJGFFY-INIZCTEOSA-N | | CAS DataBase Reference | 112068-01-6(CAS DataBase Reference) | | NIST Chemistry Reference | S-(-)-1,1-diphenylprolinol(112068-01-6) |
| | (S)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol Usage And Synthesis |
| Chemical Properties | white to beige crystals or crystalline powder | | Uses | suzuki reaction | | Uses | (S)-(-)-alpha,alpha-Diphenylprolinol is used to prepare the corresponding oxazaborolidines for the borane-mediated asymmetric reduction of ketones. | | General Description | (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol is a bifunctional organocatalyst. |
| | (S)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol Preparation Products And Raw materials |
|