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CAS:86-57-7
Purity:AR Package:10g;50g;100g;500g;1kg;5kg;25kg Remarks:99kg
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| | 1-Nitronaphthalene Basic information |
| | 1-Nitronaphthalene Chemical Properties |
| Melting point | 56 °C | | Boiling point | 304 °C(lit.) | | density | 1.223 g/mL at 25 °C(lit.) | | refractive index | 1.5200 (estimate) | | Fp | 164 °C | | storage temp. | 2-8°C | | solubility | H2O: insoluble | | form | neat | | Specific Gravity | 1.223 | | color | Light Yellow To Yellow | | Water Solubility | 0.022 g/L | | Merck | 14,6613 | | BRN | 1867714 | | Stability: | Stable. Combustible. Incompatible with oxidizing agents, strong reducing agents. Mixtures with sulfuric or nitric acid are dangerous. | | InChIKey | RJKGJBPXVHTNJL-UHFFFAOYSA-N | | CAS DataBase Reference | 86-57-7(CAS DataBase Reference) | | NIST Chemistry Reference | Naphthalene, 1-nitro-(86-57-7) | | IARC | 3 (Vol. 46) 1989 | | EPA Substance Registry System | 1-Nitronaphthalene (86-57-7) |
| | 1-Nitronaphthalene Usage And Synthesis |
| Chemical Properties | yellow crystalline solid | | Uses | Usually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents. | | Uses | 1-Nitronaphthalene as a nitroaromatic compound is studied for mutagenicity, as nitroaromatics are used in everyday products from polmers, dyes to drugs. | | Definition | ChEBI: A mononitronaphthalene substituted by a nitro group at position 1. | | General Description | 1-Nitronaphthalene is a mutagenic nitroaromatic compound present in diesel exhaust and it causes acute liver and lung toxicity in rodents. 1-Nitronaphthalene is a cytochrome P450-bioactivated, nonciliated bronchiolar epithelial (Clara) cell cytotoxicant . | | Biochem/physiol Actions | 1-Nitronaphthalene binds covalently to protein and forms adducts in the rat airway epithelium in vivo. | | Safety Profile | Poison by
intraperitoneal route. Mutation data
reported. A skin, eye, and mucous
membrane irritant. Flammable solid and
combustible liquid when exposed to heat or
flame. To fight fire, use CO2, dry chemical,
or water spray. Explosive reaction with
nitric acid + sulfuric acid above 60°C.
Forms a sensitive explosive mixture with
tetranitromethane. When heated to
decomposition it emits toxic fumes of NOx.
See also 2-NITRONAPHTHALENE and
NITRO COMPOUNDS OF AROMATIC
HYDROCARBONS. | | Purification Methods | Fractionally distil 1-nitronaphthalene under reduced pressure, then crystallise it from EtOH, aqueous EtOH or heptane. Chromatograph it on alumina with *benzene/pet ether as eluent. It sublimes in vacuo. The 1:1 picrate complex has m 72o (from EtOH). [Beilstein 5 H 553, 5 III 1593, 5 IV 1673.] |
| | 1-Nitronaphthalene Preparation Products And Raw materials |
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