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Oxalic acid dihydrate

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Oxalic acid dihydrate Basic information
Product Name:Oxalic acid dihydrate
Synonyms:Oxalate Acid;Two water oxalic acid;OXALIC ACID 2HYD XTL;Oxalic acid test solution(ChP);Has two acid;Oxalic acid dihydrate Manufacturer;OXALIC ACID SOLUTION, 10% W/VOXALIC ACID SOLUTION, 10% W/VOXALIC ACID SOLUTION, 10% W/VOXALIC ACID SOLUTION, 10% W/V;OXALIC ACID, DIHYDRATE, HIGH PURITYOXALIC ACID, DIHYDRATE, HIGH PURITYOXALIC ACID, DIHYDRATE, HIGH PURITYOXALIC ACID, DIHYDRATE, HIGH PURITY
CAS:6153-56-6
MF:C2H6O6
MW:126.07
EINECS:612-167-2
Product Categories:others;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;C1 to C5;Essential Chemicals;Inorganic Salts;Lipid Library;Metabolic Pathways;Metabolites and Cofactors on the Metabolic Pathways Chart;Reagent Plus;Research Essentials;Solutions and Reagents;Building Blocks;Carbonyl Compounds;Carboxylic Acids;Chemical Synthesis;Lipid;Metabolic Libraries;Metabolomics;Organic Building Blocks;ACS Grade
Mol File:6153-56-6.mol
Oxalic acid dihydrate Structure
Oxalic acid dihydrate Chemical Properties
Melting point 104-106 °C(lit.)
Boiling point 108-109°C
density 1,65 g/cm3
vapor density 4.4 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
Fp 157°C
storage temp. Store at +5°C to +30°C.
solubility H2O: soluble1M at 20°C, clear, colorless
form Powder/Solid
Specific Gravity1.65
color Yellow to yellow-green
PH~1.0 (25℃, 1M in H2O)
PH Range6 - 8 at 25 °C
Water Solubility 138 g/L (20 ºC)
Sublimation 157 ºC
Merck 14,6911
BRN 3679436
Exposure limitsTLV-TWA for anhydrous acid 1 mg/m3 (ACGIH, MSHA, and OSHA); TLV-STEL 2 mg/m3 (ACGIH).
Stability:Stable. Incompatible with bases, acid chlorides, steel, silver, silver compounds, moisture. Avoid contact with metals.
InChIKeyGEVPUGOOGXGPIO-UHFFFAOYSA-N
CAS DataBase Reference6153-56-6(CAS DataBase Reference)
NIST Chemistry ReferenceOxalic acid dihydrate(6153-56-6)
EPA Substance Registry SystemOxalic acid dihydrate (6153-56-6)
Safety Information
Hazard Codes Xn,C
Risk Statements 21/22-41
Safety Statements 24/25-39-37-36-26
RIDADR UN 3261 8/PG 3
WGK Germany 1
RTECS RO2450000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29171100
ToxicityLD50 orally in Rabbit: 375 mg/kg
MSDS Information
ProviderLanguage
Ethanedionic acid English
SigmaAldrich English
ACROS English
ALFA English
Oxalic acid dihydrate Usage And Synthesis
Chemical Propertieswhite crystals
UsesOxalic acid dihydrate is a purifying agent in pharmaceutical industry, special in antibiotic medication, such as Oxytetracycline , Chloramphenicol , etc; * Precipitating agent in Rare-earth mineral processing; * Bleaching agent in the textile activities, wood pulp bleaching; * Rust-remover for Metal treatment; * Grinding agent, such as Marble polishing; * Waste water treatment, removing calcium from water.
UsesA diprotic reducing agent used as a buffer.
UsesOxalic acid occurs in the cell sap of Oxalisand Rumex species of plants as the potassium and calcium salt. It is the metabolicproduct of many molds (Merck 1989). Thereare a large number of applications of thiscompound, including indigo dyeing; calicoprinting; removal of paint, rust, and inkstains; metal polishing; bleaching leather; inpesticide compositions and manufacture ofoxalates. It is also used as an analyticalreagent and as a reducing agent in organicsynthesis.
Addition of oxalic acid to chromic acid forthe anodizing of Al alloy has been reported tomodify the morphology and improve the corrosion performance of anodic films (Moutarlier et al. 2004). Also, it is a very effectiveadditive for the ozone treatment of cellulose.It prevents the degradation of cellulose fromozone bleaching.
General DescriptionOxalic acid dihydrate (OAD) crystals are reported to be monoclinic with P21/n space group. The electron density of OAD has been obtained using X-ray diffraction studies under high resolution.
Reactivity ProfileAt high temperatures oxalic acid decomposes, producing toxic carbon monoxide, andformic acid. Mixing with warm sulfuric acidmay produce the same products: CO2, CO,and formic acid. It reacts with many silvercompounds, forming explosive silver oxalate(NFPA 1986). An explosion occurred whenwater was added to an oxalic acid/sodiumchlorite mixture in a stainless steel beaker.There was also evolution of highly toxicchlorine dioxide gas (MCA 1962). Oxalicacid reacts violently with strong oxidizingsubstances.
Health HazardOxalic acid is a strong poison. The toxicsymptoms from ingestion include vomiting, diarrhea, and severe gastrointestinaldisorder, renal damage, shock, convulsions,and coma. Death may result from cardiovascular collapse. The toxicity arises asoxalic acid reacts with calcium in the tissuesto form calcium oxalate, thereby upsettingthe calcium/potassium ratio (ACGIH 1986).Deposition of oxalates in the kidney tubulesmay result in kidney damage (Hodgson et al.1988).
Oxalic acid may be absorbed into the bodythrough skin contact. It is corrosive to theskin and eyes, producing burns. Dilute solutions of 10% strength may be a mild irritantto human skin. However, the inhalation toxicity is low because of its low vapor pressure.Airborne dusts can produce eyeburn and irritation of the respiratory tract.
LD50 value, oral (rats): 375 mg/kg.
Purification MethodsCrystallise oxalic acid from distilled water. Dry it in a vacuum over H2SO4. The anhydrous acid can be obtained by drying at 100o overnight. [Beilstein 2 IV 1819.]
Tag:Oxalic acid dihydrate(6153-56-6) Related Product Information
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