페난트렌

페난트렌
페난트렌 구조식 이미지
카스 번호:
85-01-8
한글명:
페난트렌
동의어(한글):
페난트렌;페난프렌
상품명:
Phenanthrene
동의어(영문):
Phenanthren;31055;Philippines;phenanthrene, pure;ravatite;Phenantren;Phenathrene;Phenanthrenetech;phethane;Phenantrin
CBNumber:
CB8854465
분자식:
C14H10
포뮬러 무게:
178.23
MOL 파일:
85-01-8.mol

페난트렌 속성

녹는점
98-100 °C (lit.)
끓는 점
340 °C (lit.)
밀도
1.063 g/mL at 25 °C (lit.)
증기 밀도
6.14
증기압
0.00012 hPa (20 °C)
굴절률
1.5943
인화점
99-101°C
저장 조건
room temp
용해도
Soluble in alcohol, benzene, toluene, and glacial acetic acid
물리적 상태
platelets (fine)
산도 계수 (pKa)
>15 (Christensen et al., 1975)
색상
brown
수용성
insoluble
Merck
14,7212
BRN
1905428
Henry's Law Constant
0.49, 1.80, 3.35, and 7.89 at 5, 15, 25, and 35 °C, respectively (gas stripping-GC, Odabasi et al., 2006)
노출 한도
OSHA: TWA 0.2 mg/m3
안정성
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS 데이터베이스
85-01-8(CAS DataBase Reference)
NIST
Phenanthrene(85-01-8)
IARC
3 (Vol. Sup 7, 92) 2010
EPA
Phenanthrene (85-01-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,F,T
위험 카페고리 넘버 22-36/37/38-50-50/53-40-67-65-38-11-52/53-39/23/24/25-23/24/25-63-43-45-20/21/22-20
안전지침서 26-60-61-36/37-29-62-45-16-7-24/25-23-53-37/39-22-33-25-9
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 2
RTECS 번호 SF7175000
F 고인화성물질 8
자연 발화 온도 >450 °C
TSCA Yes
HS 번호 2902 90 00
위험 등급 9
포장분류 III
유해 물질 데이터 85-01-8(Hazardous Substances Data)
독성 LD50 i.p. in mice: 700 mg/kg (IARC)
기존화학 물질 KE-28202
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P391 누출물을 모으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1
1 0

페난트렌 C화학적 특성, 용도, 생산

개요

Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) composed of three fused benzene rings. The name phenanthrene is a composite of phenyl and anthracene. In its pure form, it is found in cigarette smoke and is a known irritant, photosensitizing skin to light. Phenanthrene appears as a white powder having blue fluorescence.

화학적 성질

Phenanthrene is a white crystalline substance. Weak aromatic odor. Polycyclic aromatic hydrocarbons (PAHs) are compounds containing multiple benzene rings and are also called polynuclear aromatic hydrocarbons.

물리적 성질

Colorless, monoclinic crystals with a faint, aromatic odor

용도

Phenanthrene is a polycyclic aromatic hydrocarbons, an environmental pollutant.

정의

ChEBI: A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene.'

생산 방법

Phenanthrene occurs in coal tar and can be isolated from several types of crude petroleum.

일반 설명

Colorless monoclinic crystals with a faint aromatic odor. Solutions exhibit a blue fluorescence.

공기와 물의 반응

Insoluble in water.

반응 프로필

Phenanthrene may react with oxidizing materials .

건강위험

The acute oral toxicity of phenanthrene is low.It is more toxic than anthracene. An oral LD50value in mice is reported at 700 mg/kg. It maycause tumor in skin at the site of application.The evidence of carcinogenicity in animals,however, is inadequate.

화재위험

Phenanthrene is combustible.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. Mutation data reported. A human skin photosensitizer. Questionable carcinogen with experimental neoplastigenic and tumorigenic data by skin contact. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes

잠재적 노출

Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

Carcinogenicity

Phenanthrene is ineffective as an initiator. It is not classifiable as to human carcinogenicity— class 3 by IARC and class D by IRIS, based on no human data and inadequate data from a single gavage study in rats and skin painting and injection studies in mice.

운송 방법

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

폐기물 처리

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

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