노르말헥산
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노르말헥산 속성
- 녹는점
- -95 °C
- 끓는 점
- 68.95 °C(lit.)
- 밀도
- 0.659 g/mL at 25 °C(lit.)
- 증기 밀도
- 3.5 (vs air)
- 증기압
- 40 mm Hg ( 20 °C)
- 굴절률
- n
20/D 1.388
- 인화점
- 30 °F
- 저장 조건
- Store at +5°C to +30°C.
- 용해도
- Very soluble in ethanol, ethyl ether and chloroform.
- 물리적 상태
- Liquid
- 산도 계수 (pKa)
- >14 (Schwarzenbach et al., 1993)
- Specific Gravity
- 0.660 (20/4℃)
- 색상
- Colorless
- 냄새
- Mild gasoline-like odor detectable at 65 to 248 ppm
- 상대극성
- 0.009
- 폭발한계
- 1.0-8.1%(V)
- Odor Threshold
- 1.5ppm
- 수용성
- insoluble
- 최대 파장(λmax)
- λ: 200 nm Amax: ≤0.70
λ: 225 nm Amax: ≤0.10
λ: 250 nm Amax: ≤0.01
- Merck
- 14,4694
- BRN
- 1730733
- Henry's Law Constant
- 0.238, 0.413, 0.883, 0.768, and 1.56 at 10, 15, 20, 25, and 30 °C, respectively (EPICS, Ashworth et al., 1988)
- 노출 한도
- TLV-TWA 50 ppm (~175 mg/m3) (ACGIH), 500 ppm (~1750 mg/m3) (OSHA); IDLH 5000 ppm (NIOSH).
- 안정성
- Stable. Incompatible with oxidizing agents, chlorine, fluorine, magnesium perchlorate. Highly flammable. Readily forms explosive mixtures with air. Note low flash point.
- InChIKey
- VLKZOEOYAKHREP-UHFFFAOYSA-N
- LogP
- 4 at 20℃ and pH7
- CAS 데이터베이스
- 110-54-3(CAS DataBase Reference)
- NIST
- Hexane(110-54-3)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,Xn,N | ||
---|---|---|---|
위험 카페고리 넘버 | 11-38-50/53-65-67-62-51/53-48/20-36/37/38 | ||
안전지침서 | 9-16-29-33-60-61-62-36/37-45-36/37/39-53-26 | ||
유엔번호(UN No.) | UN 3295 3/PG 2 | ||
WGK 독일 | 3 | ||
RTECS 번호 | MN9275000 | ||
F 고인화성물질 | 3-10 | ||
자연 발화 온도 | 225 °C | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | II | ||
HS 번호 | 29011000 | ||
유해 물질 데이터 | 110-54-3(Hazardous Substances Data) | ||
독성 | LC50 (4 hr) in mice by inhalation: 48000 ppm; LD50 orally in rats: 32.0 g/kg (Couri, Milks) | ||
IDLA | 1,100 ppm [10% LEL] | ||
기존화학 물질 | KE-18626 |
노르말헥산 C화학적 특성, 용도, 생산
화학적 성질
n-Hexane is a highly flammable liquid, usually isolated from crude oil, and has extensive industrial applications as a solvent in adhesive bandage factories and other industries.It is highly toxic, triggering several adverse health effects, i.e., nausea, skin irritation, dizziness, numbness of limbs, CNS depression, vertigo, and respiratory tract irritation to animals and humans. Occupational exposure of industrial workers has demonstrated motor polyneuropathy. Workers associated with long-term glue sniffi ng showed adverse effects in the form of degeneration of axons and nerve terminals.
물리적 성질
Clear, colorless, very flammable liquid with a faint, gasoline-like odor. An odor threshold concentration of 1.5 ppmv was reported by Nagata and Takeuchi (1990).용도
n-Hexane is a chief constituent of petroleumether, gasoline, and rubber solvent. It is usedas a solvent for adhesives, vegetable oils,and in organic analysis, and for denaturingalcohol.정의
ChEBI: An unbranched alkane containing six carbon atoms.일반 설명
Clear colorless liquids with a petroleum-like odor. Flash points -9°F. Less dense than water and insoluble in water. Vapors heavier than air. Used as a solvent, paint thinner, and chemical reaction medium.공기와 물의 반응
Highly flammable. Insoluble in water.반응 프로필
HEXANE may be sensitive to light. Hexane may also be sensitive to prolonged exposure to heat. Hexane can react vigorously with oxidizing materials. This would include compounds such as liquid chlorine, concentrated O2, sodium hypochlorite and calcium hypochlorite. Hexane is also incompatible with dinitrogen tetraoxide. Hexane will attack some forms of plastics, rubber and coatings. .위험도
Flammable, dangerous fire risk.건강위험
n-Hexane is a respiratory tract irritant andat high concentrations a narcotic. Its acutetoxicity is greater than that of n-pentane.Exposure to a concentration of 40,000 ppmfor an hour caused convulsions and death inmice. In humans a 10-minute exposure toabout 5000 ppm may produce hallucination,distorted vision, headache, dizziness, nausea,and irritation of eyes and throat. Chronicexposure to n-hexane may cause polyneuritis.The metabolites of n-hexane injected inguinea pigs were reported as 2,5- hexanedioneand 5-hydroxy-2-hexanone, which arealso metabolites of methyl butyl ketone(DiVincenzo et al. 1976). Thus methyl butylketone and n- hexane should have similartoxicities. The neurotoxic metabolite, 2,5-hexanedione, however, is produced considerablyless in n-hexane. However, in the caseof hexane, the neurotoxic metabolite 2,5-hexanedione is produced to a much lesserextent. Continuous exposure to 250 ppmn-hexane produced neurotoxic effects in animals. Occupational exposure to 500 ppmmay cause polyneuropathy (ACGIH 1986).
Inhalation of n-hexane vapors have shownreproductive effects in rats and mice.
인화성 및 폭발성
Hexane is extremely flammable (NFPA rating = 3), and its vapor can travel a considerable distance to an ignition source and "flash back." Hexane vapor forms explosive mixtures with air at concentrations of 1.1 to 7.5 % (by volume).Hydrocarbons of significantly higher molecular weight have correspondingly higher vapor pressures and therefore present a reduced flammability hazard. Carbon dioxide or dry chemical extinguishers should be used for hexane fires.
화학 반응
Reactivity with Water: No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.잠재적 노출
n-Hexane is industrial chemical, emul sifier, in manufacture of plastics, resins; as a solvent, par ticularly in the extraction of edible fats and oils; as a laboratory reagent; and as the liquid in low temperature thermometers. Technical and commercial grades consist of 45 85% hexane, as well as cyclopentanes, isohexane, and 1% to 6% benzene.Carcinogenicity
Male rabbits exposed to 3000 ppm hexane (8 h/day, 6 days/week for 24 weeks) developed papillary proliferation of nonciliated bronchiolar cells. No tumors were found in mice painted with hexane and croton oil as cocarcinogen, presumably for the lifetime of each animal. Hexane is inactive as a tumorpromoting agent.환경귀착
Biological. Hexane may biodegrade in two ways. The first is the formation of hexyl hydroperoxide, which decomposes to 1-hexanol followed by oxidation to hexanoic acid. The other pathway involves dehydrogenation to 1-hexene, which may react with water giving 1-hexanol (Dugan, 1972). Microorganisms can oxidize alkanes under aerobic conditions (Singer and Finnerty, 1984). The most common degradative pathway involves the oxidation of the terminal methyl group forming 1-hexanol. The alcohol may undergo a series of dehydrogenation steps forming a hexanal followed by oxidation to form hexanoic acid. The fatty acid may then be metabolized by β-oxidation to form the mineralization products, carbon dioxide and water (Singer and Finnerty, 1984).Photolytic. An aqueous solution irradiated by UV light at 50 °C for 1 d resulted in a 50.51% yield of carbon dioxide (Knoevenagel and Himmelreich, 1976). Synthetic air containing gaseous nitrous acid and exposed to artificial sunlight (λ = 300–450 nm) photooxidized hexane into two isomers of hexyl nitrate and peroxyacetal nitrate (Cox et al., 1980).
Chemical/Physical. Complete combustion in air yields carbon dioxide and water vapor.
저장
hexane should be used only in areas free of ignition sources, and quantities greater than 1 liter should be stored in tightly sealed metal containers in areas separate from oxidizers.운송 방법
UN1208 Hexanes, Hazard Class: 3; Labels: 3-Flammable liquid.Purification Methods
Purify as for n-heptane. Modifications include the use of chlorosulfonic acid or 35% fuming H2SO4 instead of conc H2SO4 in washing the alkane, and final drying and distilling from sodium hydride. Unsaturated impurities can be removed by shaking the hexane with nitrating acid (58% H2SO4, 25% conc HNO3, 17% water, or 50% HNO3, 50% H2SO4), then washing the hydrocarbon layer with conc H2SO4, followed by H2O, drying, and distilling over sodium or n-butyl lithium. It can also be purified by distillation under nitrogen from sodium benzophenone ketyl solubilised with tetraglyme. Also purify it by passage through a silica gel column followed by distillation [Kajii et al. J Phys Chem 91 2791 1987]. It is a FLAMMABLE liquid and a possible nerve toxin. [Beilstein 1 IV 338.] Rapid purification: Distil, discarding the first forerun and stored over 4A molecular sieves.비 호환성
May form explosive mixture with air. Contact with strong oxidizers may cause fire and explo sions. Contact with dinitrogen tetraoxide may explode @ 28℃.Attacks some plastics, rubber and coatings. May accumulate static electrical charges, and may cause ignition of its vapors.폐기물 처리
Dissolve or mix the material with a combustible solvent and burn in a chemical incinera tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.노르말헥산 준비 용품 및 원자재
원자재
준비 용품
RAPESEEDOIL,SUPERGLYCERINATED,FULLYHYDROGENATED
2-(2-ISOPROPYLPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
Mono-caprylin glycerate
1-Methyl-2-imidazolecarboxaldehyde
Maize yellIow
2-(4-chlorop henyl)-4,5-dihydro-1-methyl-5-(trifluoromethyl)-1H-pyr role-3-carbonitrile
(1R,3S)-3-Aminocyclopentanecarboxylic acid
1,1′-페로센다이카르복스알데하이드
CANOLA OIL
1 1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
(2,2-DIMETHYL-PROPYL)-HYDRAZINE
N-메틸-o-톨루이딘
3-CHLORO-BENZO[B]THIOPHENE-2-CARBOXYLIC ACID HYDRAZIDE
1,2-Bis(dimethylsilyl)benzene
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
5-Bromopicolinic acid
TERT-BUTYL 4-FORMYL-2-METHOXYPHENYL CARB ONATE, 99
TERT-BUTYL 3-FORMYLPYRIDIN-4-YLCARBAMATE
CYANOMETHYLENETRIBUTYLPHOSPHORANE
2,5-Dichloroisonicotinic acid
3-CHLOROBENZO[B]THIOPHENE-2-CARBONYL CHLORIDE
Capsicum red pigment
카르니틴타트레이트
METHYL 3-CHLOROBENZO[B]THIOPHENE-2-CARBOXYLATE
3-CHLOROBENZO[B]THIOPHENE-2-CARBOXYLIC ACID
아나토
3-ACETOXYBENZOIC ACID
BIS(DIETHYLAMINO)CHLOROPHOSPHINE
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&
4-BOCAMINO-NICOTINIC ACID
1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
Pefurazoate
3,4-DIHYDRO-2H-1,5-BENZODIOXEPINE-7-CARBALDEHYDE
(1R,4S)-4-Aminocyclopent-2-enecarboxylic acid
2'-BROMOACETANILIDE
5-Chloro-2-nitrobenzaldehyde
(3-HYDROXYMETHYL-PYRIDIN-4-YL)-CARBAMIC ACID TERT-BUTYL ESTER
[Bis(trifluoroacetoxy)iodo]benzene
1-(2-Methoxyphenyl)piperazine
ETHYL 4-HYDROXY-7-(TRIFLUOROMETHYL)QUINOLINE-3-CARBOXYLATE
노르말헥산 공급 업체
글로벌( 764)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
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AS WATER CO., LTD. | +86-18994963526 +8618994963526 |
1346073549@qq.com | United Kingdom | 173 | 58 |
Shandong Yanshuo Chemical Co., Ltd. | +86-18678179670 +86-18615116763 |
sales@yanshuochem.com | China | 101 | 58 |
HENAN LIHAO CHEM PLANT LIMITED | +86-0371-88812595 +8618703631882 |
info@lihaochemical.com | China | 35476 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29811 | 60 |
Shanghai Bojing Chemical Co.,Ltd. | +86-86-02137122233 +8613795318958 |
bj1@bj-chem.com | China | 296 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21975 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 31969 | 60 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 |
info@tnjchem.com | China | 2990 | 55 |
Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 |
kaia@neputrading.com | China | 1011 | 58 |
HEBEI YINGONG NEW MATERIAL TECHNOLOGY CO.,LTD | +86-19933070948 +86-19930599843 |
claire@hbyingong.com | China | 945 | 58 |